Articles with "ion promoted" as a keyword



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Metal ion-promoted fabrication of melanin-like poly(L-DOPA) nanoparticles for photothermal actuation

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Published in 2020 at "Science China Chemistry"

DOI: 10.1007/s11426-020-9797-3

Abstract: Melanin-inspired polymers are currently the focus of growing interest for a wide range of applications ranging from energy to biomedical area. Whilst researchers have made numerous attempts to prepare and utilize polydopamine nanoparticles (PDA NPs),… read more here.

Keywords: melanin; dopa nps; metal ion; melanin like ... See more keywords

Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c00011

Abstract: A trityl-cation-initiated, silylium-ion-promoted hydrosilylation of aryl-substituted allenes is reported. Depending on the hydrosilane-to-initiator ratio, the hydrosilylation can be intercepted by an intramolecular electrophilic aromatic substitution or a Nazarov electrocyclization of an allyl-cation intermediate in the… read more here.

Keywords: hydrosilylation; silylium ion; hydrosilylation aryl; cation ... See more keywords