Rare Earth Metal Ion‐Doped Halide Solid Electrolytes plus Ta5+ Substitution for Long Cycling All‐Solid‐State Batteries
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DOI: 10.1002/adfm.202426053
Abstract: Li2ZrCl6 (LZC) solid electrolyte has been recognized as a promising candidate for all‐solid‐state batteries (ASSBs), owing to its remarkable compatibility with high‐voltage cathodes and the cost advantage among halide electrolytes. However, the ionic conductivity of… read more here.
Keywords: rare earth; earth metal; state batteries; ionic conductivity ... See more keywords
Designing Optimal Perovskite Structure for High Ionic Conduction.
Sign Up to like & getrecommendations! Published in 2019 at "Advanced materials"
DOI: 10.1002/adma.201905178
Abstract: Solid-oxide fuel/electrolyzer cells are limited by a dearth of electrolyte materials with low ohmic loss and an incomplete understanding of the structure-property relationships that would enable the rational design of better materials. Here, using epitaxial… read more here.
Keywords: ionic conductivity; unit cell; octahedral rotations; cell volume ... See more keywords
Unlocking Fast Lithium Ion Migration in Zirconium‐Based Fluoride Solid Electrolytes
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DOI: 10.1002/adma.202508314
Abstract: Fluoride solid‐state electrolytes (SSEs) have attracted significant interest due to the extremely high oxidation limits, excellent air stability, and favorable compatibility with metallic lithium, while the structure‐property relationship remains unknown. Although crystalline Li2ZrF6 (LZF) synthesized… read more here.
Keywords: lithium; ionic conductivity; fluoride solid; zirconium based ... See more keywords
Aligned Ionogel Electrolytes for High‐Temperature Supercapacitors
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DOI: 10.1002/advs.201801337
Abstract: Abstract Ionogels are a new class of promising materials for use in all‐solid‐state energy storage devices in which they can function as an integrated separator and electrolyte. However, their performance is limited by the presence… read more here.
Keywords: ionic conductivity; ionogel electrolytes; high temperature; electrolytes high ... See more keywords
Understanding Enhanced Ionic Conductivity in Composite Solid-State Electrolyte in a Wide Frequency Range of 10-2 -1010 Hz.
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DOI: 10.1002/advs.202200213
Abstract: The ionic conductivity of composite solid-state electrolytes (SSEs) can be tuned by introducing inorganic fillers, of which the mechanism remains elusive. Herein, ion conductivity of composite SSEs is characterized in an unprecedentedly wide frequency range… read more here.
Keywords: composite solid; ionic conductivity; solid state; conductivity ... See more keywords
Lithium Superionic Conduction in BH4‐Substituted Thiophosphate Solid Electrolytes
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DOI: 10.1002/advs.202204942
Abstract: Compared with conventional liquid electrolytes, solid electrolytes can better improve the safety properties and achieve high‐energy‐density Li‐ion batteries. Sulfide‐based solid electrolytes have attracted significant attention owing to their high ionic conductivities, which are comparable to… read more here.
Keywords: thiophosphate solid; lithium superionic; thiophosphate local; solid electrolytes ... See more keywords
Wet Chemistry Route to Li3InCl6: Microstructural Control Render High Ionic Conductivity and Enhanced All‐Solid‐State Battery Performance
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DOI: 10.1002/advs.202403208
Abstract: Thanks to superionic conductivity and compatibility with >4 V cathodes, halide solid electrolytes (SEs) have elicited tremendous interest for application in all‐solid‐state lithium batteries (ASSLBs). Many compositions based on groups 3, 13, and divalent metals,… read more here.
Keywords: chemistry; conductivity; ionic conductivity; route ... See more keywords
Stable Seamless Interfaces and Rapid Ionic Conductivity of Ca–CeO 2 /LiTFSI/PEO Composite Electrolyte for High‐Rate and High‐Voltage All‐Solid‐State Battery
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DOI: 10.1002/aenm.202000049
Abstract: Stable and seamless interfaces among solid components in all-solid-state batteries (ASSBs) are crucial for high ionic conductivity and high rate performance. This can be achieved by the combination of functional inorganic material and flexible polymer… read more here.
Keywords: ionic conductivity; solid state; peo; conductivity ... See more keywords
Breaking the Trade‐Off between Ionic Conductivity and Mechanical Strength in Solid Polymer Electrolytes for High‐Performance Solid Lithium Batteries
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DOI: 10.1002/aenm.202400808
Abstract: Solid polymer electrolytes (SPEs) are among the most promising candidates for solid‐state batteries due to their easy processibility, interface compatibility, and cost efficiency. However, the trade‐off between the ionic conductivity and mechanical strength of SPEs,… read more here.
Keywords: ionic conductivity; mechanical strength; solid state;
Unraveling the Fast Ionic Conduction in NASICON‐Type Materials
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DOI: 10.1002/aenm.202403877
Abstract: Na Superionic Conductor (NASICON) materials stand out as an important class of ionic conductors, offering high ionic conductivity and notable electrochemical stability for applications such as solid electrolytes. While advances through compositional engineering have been… read more here.
Keywords: ionic conduction; ionic conductivity; site ordering; conduction ... See more keywords
Chemical and Electrochemical Characterization of Hot-Pressed Li6PS5Cl Solid State Electrolyte: Operating Pressure-Invariant High Ionic Conductivity.
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DOI: 10.1002/cssc.202400718
Abstract: Sulfide solid state electrolytes (SSE) are among the most promising materials in the effort to replace liquid electrolytes, largely due to their comparable ionic conductivities. Among the sulfide SSEs, Argyrodites (Li6PS5X, X=Cl, Br, I) further… read more here.
Keywords: spectroscopy; ionic conductivity; solid state; state electrolyte ... See more keywords