Non‐Globular Organic Ionic Plastic Crystal Containing a Crown‐Ether Moiety – Tuning Its Behaviour Using Sodium Salts
Sign Up to like & getrecommendations! Published in 2022 at "Chemphyschem"
DOI: 10.1002/cphc.202200258
Abstract: Abstract Organic ionic plastic crystals (OIPCs) are a class of soft materials showing positional order while still allowing orientational freedom. Due to their motional freedom in the solid state, they possess plasticity, non‐flammability and high… read more here.
Keywords: crown ether; organic ionic; ether moiety; non globular ... See more keywords
Pyrrolidinium-based organic ionic plastic crystals: Relationship between side chain length and properties
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2019.02.076
Abstract: Abstract Organic ionic plastic crystals (OIPCs) have been studied as solid-state electrolytes because of their desirable properties such as non-flammability, plasticity, and ionic conductivity. However, the temperature range of their conductive plastic crystal phase is… read more here.
Keywords: chain; plastic; plastic crystals; fsa ... See more keywords
Ternary lithium-salt organic ionic plastic crystal polymer composite electrolytes for high voltage, all-solid-state batteries
Sign Up to like & getrecommendations! Published in 2018 at "Energy Storage Materials"
DOI: 10.1016/j.ensm.2018.07.017
Abstract: Abstract Organic ionic plastic crystals (OIPCs) are a promising class of solid electrolyte material and recent reports of high concentration Li-containing OIPCs are drawing attention due to their enhanced performance. In this report, nano-sized poly(vinylidene… read more here.
Keywords: organic ionic; ternary lithium; ionic plastic; plastic crystal ... See more keywords
Ionic plastic crystal-polymeric ionic liquid solid-state electrolytes with high ionic conductivity for lithium ion batteries
Sign Up to like & getrecommendations! Published in 2019 at "Materials Letters"
DOI: 10.1016/j.matlet.2018.11.003
Abstract: Abstract A new organic ionic plastic crystal triethylmethylammonium bis(fluorosulfonyl)imide (N1222FSI) was successfully synthesized and introduced into the polymeric ionic liquid (PIL)/LiTFSI system to prepare a novel series of N1222FSI-PIL-LiTFSI solid polymer electrolytes (SPEs). The SPEs… read more here.
Keywords: polymeric ionic; ionic conductivity; conductivity; ionic plastic ... See more keywords
Predicting gas selectivity in organic ionic plastic crystals by free energy calculations
Sign Up to like & getrecommendations! Published in 2021 at "RSC Advances"
DOI: 10.1039/d1ra01844b
Abstract: Organic ionic plastic crystals (OIPCs) are molecularly disordered solids, and their potential for the development of gas separation membranes has recently been demonstrated. Here, the gas absorption capability of the OIPC, diethyl(methyl)(isobutyl)phosphonium hexafluorophosphate ([P122i4][PF6]), for… read more here.
Keywords: energy; plastic crystals; selectivity; gas ... See more keywords
Understanding the barocaloric response of choline-based hybrid ionic plastic crystals [choline] 2 CoCl 4 and [choline] 2 ZnCl 4
Sign Up to like & getrecommendations! Published in 2025 at "Journal of Materials Chemistry A"
DOI: 10.1039/d5ta05423k
Abstract: Traditional refrigeration methods based on vapor compression are environmentally damaging, prompting a need for greener alternatives. Hybrid ionic plastic crystals that exhibit order-disorder structural phase transitions around room temperature with... read more here.
Keywords: understanding barocaloric; plastic crystals; choline; hybrid ionic ... See more keywords
Phase Transition and Ionic Conductivity of Pyrrolidinium-Based Ionic Plastic Crystals with Magnesium Salts
Sign Up to like & getrecommendations! Published in 2024 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1093/bulcsj/uoae101
Abstract: Despite being safe for use in secondary Mg batteries, solid electrolytes exhibit lower ionic conductivities than those of traditional liquid electrolytes. Organic ionic plastic crystals (OIPCs)—soft crystals with excellent thermal and electrochemical stabilities and ionic… read more here.
Keywords: phase transition; pyrrolidinium based; conductivity; ionic conductivity ... See more keywords
Organic ionic plastic crystals having colossal barocaloric effects for sustainable refrigeration.
Sign Up to like & getrecommendations! Published in 2025 at "Science"
DOI: 10.1126/science.adq8396
Abstract: Barocaloric (BC) materials offer the potential for highly energy-efficient refrigeration by generating heat absorption through the effect of pressure on a solid-solid phase transition. However, very few of the known materials have the required phase… read more here.
Keywords: refrigeration; plastic crystals; crystals colossal; ionic plastic ... See more keywords
1H and 13C NMR Studies on New Ionic Plastic Crystals Constructed by Ellipsoidal Cations with [BEt3Me] Anion
Sign Up to like & getrecommendations! Published in 2019 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1246/bcsj.20180320
Abstract: Two new ionic plastic crystals of [NEtMe2Pr][BEt3Me] and [NEt2MePr][BEt3Me] were found. In contrast, the highest-temperature solid-phase of [NEtMe2Bu][BEt3Me] and [NEt2MeBu][BEt3Me] were assigned t... read more here.
Keywords: new ionic; plastic crystals; 13c nmr; nmr studies ... See more keywords