Complex formation of silver(I) ions with a glucosinolate derivative: structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage.
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DOI: 10.1039/d1dt00695a
Abstract: The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of… read more here.
Keywords: silver ions; ions glucosinolate; bond; complex formation ... See more keywords