C(sp2)–F Oxidative Addition of Fluorinated Aryl Ketones by iPrPCPIr
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DOI: 10.1021/acs.organomet.7b00466
Abstract: The reaction of iPrPCPIrH4 (iPrPCP = κ3-2,6-C6H3(CH2P(iPr)2)2) with ≥2 equiv of 2,3,4,5,6-pentafluoroacetophenone (AP-F5) in aromatic solvents at room temperature leads to the hydrogenation of AP-F5 and formation of the corresponding 5-coordinate alkoxy hydride species (I)… read more here.
Keywords: oxidative addition; product iprpcpir; iprpcpir oc8h3f4; formation ... See more keywords