Iridium-induced regioselective B-H and C-H activations at azo-substituted m-carboranes: facile access to polynuclear complexes.
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DOI: 10.1039/c8cc09084j
Abstract: Iridium(iii)-induced selective B(2,3)-H and C-H bond activations at mono- and bi-p-methoxybenzeneazo-substituted m-carboranes have been investigated. A powerful methodology is introduced for the preparation of unique polynuclear complexes featuring m-carboranyl ligands in a single step. The… read more here.
Keywords: polynuclear complexes; induced regioselective; substituted carboranes; iridium induced ... See more keywords