Extraction and Separation of Iridium(IV) and Rhodium(III) from Hydrochloric Acid Media by a Quaternary Ammonium-Based Hydrophobic Eutectic Solvent
Sign Up to like & getrecommendations! Published in 2021 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2021.118814
Abstract: Abstract The extraction and separation of iridium(IV) and rhodium(III) from hydrochloric acid solutions by a hydrophobic eutectic solvent composed of tetraheptylammonium chloride and decanoic acid have been studied for the first time. This eutectic solvent… read more here.
Keywords: iridium rhodium; separation; rhodium iii; extraction ... See more keywords
Iridium(I)– and Rhodium(I)–Olefin Complexes Containing an α-Diimine Supporting Ligand
Sign Up to like & getrecommendations! Published in 2022 at "Organometallics"
DOI: 10.1021/acs.organomet.2c00036
Abstract: Iridium(I) complexes of the type IrX(olefin)(α-diimine) (α-diimine = 1,4-bis(2,6-xylyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; X = Cl, I, Me, O2CCF3; olefin = ethylene, cyclooctene (COE)) were synthesized from the readily available precursor [IrCl(COE)2]2. These complexes display unusual 1H NMR spectra… read more here.
Keywords: olefin complexes; diimine; iridium rhodium; rhodium ... See more keywords