Half-sandwich iridium(III) complexes with α-picolinic acid frameworks and antitumor applications.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.12.012
Abstract: Eight half-sandwich iridiumIII (IrIII) complexes of the general formula [(η5-Cpxbiph)Ir(O^N)Cl] (Cpxbiph is tetramethyl(biphenyl)cyclopentadienyl, and the O^N is α-picolinic acid chelating ligand and its derivatives) were synthesized and characterized. Compared with cis-platin widely used in clinic,… read more here.
Keywords: half sandwich; iriii complexes; picolinic acid;
Synthesis and Reactivity of IrIII Complexes Bearing C-Metalated Pyrazolato Ligands
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00856
Abstract: A bidentate triazolinylidene-pyrazole chelate ligand was metalated with [IrCp*Cl2]2 to give C,N-chelate complex [4]I. The N1-metalated pyrazole subsequently underwent a rollover metalation to give the complex with C5,C4-metalated pyrazolato ligand [5]. The reactivity of [5]… read more here.
Keywords: reactivity iriii; synthesis reactivity; metalated pyrazolato; reactivity ... See more keywords