LDL dinitrosyl iron complex acts as an iron donor in mouse macrophages.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.08.004
Abstract: [Fe(NO)2] - modified nanoparticles of low-density protein (DNICLDL) can serve as conveyors of iron in the form of stable complexes with ApoB100 protein. As reported recently, in human hepatoma cells DNICLDL significantly increased the total… read more here.
Keywords: iron complex; acts iron; ldl dinitrosyl; dinitrosyl iron ... See more keywords
Reactivity of a Unique Si(I)–Si(I)-Based η2-Bis(silylene) Iron Complex
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01369
Abstract: In this paper, we report the synthesis of a unique silicon(I)-based metalla-disilirane and report on its reactivity toward TMS-azide and benzophenone. Metal complexes containing disilylenes ((bis)silylenes with a Si–Si bond) are known, but direct ligation… read more here.
Keywords: unique based; iron; reactivity unique; iron complex ... See more keywords
Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02383
Abstract: Addition of NO to a nonheme dithiolate-ligated iron(II) complex, FeII(Me3TACN)(S2SiMe2) (1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a metastable six-coordinate {FeNO}7 intermediate (S = 3/2) that was trapped at -135 °C… read more here.
Keywords: thiolate ligated; ligated iron; reduction n2o; iron complex ... See more keywords
Selective Alkane C–H Bond Oxidation Catalyzed by a Non-Heme Iron Complex Featuring a Robust Tetradentate Ligand
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00611
Abstract: An iron complex, [FeII(BpyPY2Me)(CH3CN)2](OTf)2 (1-Fe, where BpyPY2Me is 6-(1,1-di(pyridin-2-yl)ethyl)-2,2′-bipyridine and OTf is triflate), supported by an oxidatively rugged tetradentate ligand is reported for the catalytic oxidation of unactivated C–H bonds in cyclohexane and adamantane. With… read more here.
Keywords: iron complex; oxidation; heme iron; iron ... See more keywords
A Photoreactive Iron(II) Complex Luminophore.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13083
Abstract: Controlling the order and lifetimes of electronically excited states is essential to effective light-to-potential energy conversion by molecular chromophores. This work reports a luminescent and photoreactive iron(II) complex, the first performant group homologue of prototypical… read more here.
Keywords: state; iron; iron complex; photoreactive iron ... See more keywords
Si-H Bond Activation and Dehydrogenative Coupling of Silanes across the Iron-Amide Bond of a Bis(amido)bis(phosphine) Iron(II) Complex.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12157
Abstract: Despite the utility of Si-Si bonds, there are relatively few examples of Si-Si bond formation by base metals. In this work, a four-coordinate iron complex, (PNNP)FeII, is shown to strongly activate the Si-H bonds in… read more here.
Keywords: bis; iron; iron complex; bond activation ... See more keywords
An S = 1/2 Iron Complex Featuring N2, Thiolate, and Hydride Ligands: Reductive Elimination of H2 and Relevant Thermochemical Fe-H Parameters.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b02603
Abstract: Believed to accumulate on the Fe sites of the FeMo-cofactor (FeMoco) of MoFe-nitrogenase under turnover, strongly donating hydrides have been proposed to facilitate N2 binding to Fe and may also participate in the hydrogen evolution… read more here.
Keywords: hydride; iron complex; complex featuring; featuring thiolate ... See more keywords
Polymorphism of a chiral iron(ii) complex: spin-crossover and ferroelectric properties.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01634d
Abstract: Two solvent-free polymorphs of a chiral iron(ii) complex have been obtained, and their polymorphism dependent spin-crossover and ferroelectric properties have been demonstrated. Polymorph I shows a gradual spin-crossover behavior, whereas polymorph II remains in a… read more here.
Keywords: iron complex; ferroelectric properties; spin crossover; spin ... See more keywords
Direct monitoring of spin transitions in a dinuclear triple-stranded helicate iron(ii) complex through X-ray photoelectron spectroscopy.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04190j
Abstract: A dinuclear helical iron(ii) complex of a new ditopic thiazolylimine ligand (L) has been synthesised via supramolecular assembly. The resulting dinuclear helical cylinder [Fe2L3]·4BF4 was investigated by variable temperature X-ray crystallography, ESI high resolution mass… read more here.
Keywords: iron complex; spin; spectroscopy; ray photoelectron ... See more keywords
Electrocatalytic alcohol oxidation by a molecular iron complex.
Sign Up to like & getrecommendations! Published in 2022 at "Faraday discussions"
DOI: 10.1039/d1fd00074h
Abstract: An efficient electrochemical method for the selective oxidation of alcohols to their corresponding aldehydes/ketones using a biomimetic iron complex, [(bTAML)FeIII-OH2]-, as the redox mediator in an undivided electrochemical cell with inexpensive carbon and nickel electrodes… read more here.
Keywords: reaction; electrocatalytic alcohol; oxidation; iron complex ... See more keywords
Iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) suitable for surface deposition
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1430790
Abstract: Abstract The synthesis, structural and magnetic characterization of the tris iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) ligand are reported in [Fe(ppCOOH)3](ClO4)2·0.5H2O·2EtOH. Single crystal structure and magnetic characterization of the bulk compound show that the low-spin… read more here.
Keywords: iron complex; pyrazol pyridine; pyridine carboxylic; carboxylic acid ... See more keywords