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Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b03177
Abstract: EgtB is a nonheme iron enzyme catalyzing the C-S bond formation between γ-glutamyl cysteine (γGC) and N-α-trimethyl histidine (TMH) in the ergothioneine biosynthesis. Density functional calculations were performed to elucidate and delineate the reaction mechanism…
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Keywords:
mechanism;
iron enzyme;
bond;
iron ... See more keywords