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   Articles with "iron hydride" as a keyword



Synthesis and reactivity of silyl iron hydride via Si H bond activation

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recommendations! Published in 2017 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2016.10.017

Abstract: Abstract The preligand pyridine-2-amino(methyl)-dimethylsilane (1) was used to synthesize silyl iron hydride. Iron(II) hydride FeH(N(κN-C5H4N)Me(SiMe2))(PMe3)3 (2) was obtained through the reaction of 1 and Fe(PMe3)4 via the activation of one Si H bond and the… read more here.

Keywords: pme3; sime2 pme3; bond; iron hydride ... See more keywords

Low-Coordinate Iron Hydride Chemistry at an N,N,C-Heteroscorpionate Platform

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recommendations! Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.4c01596

Abstract: Locally high-spin iron hydrides are proposed to play a critical role as intermediates in iron–molybdenum cofactor (FeMoco)-catalyzed N2 fixation. Inspired by these biological systems, we report herein our initial investigations into low-coordinate iron hydride chemistry… read more here.

Keywords: chemistry; low coordinate; iron; iron hydride ... See more keywords

Hexagonal Close-packed Iron Hydride behind the Conventional Phase Diagram

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recommendations! Published in 2019 at "Scientific Reports"

DOI: 10.1038/s41598-019-48817-7

Abstract: Hexagonal close-packed iron hydride, hcp FeH x , is absent from the conventional phase diagram of the Fe–H system, although hcp metallic Fe exists stably over extensive temperature (T) and pressure (P) conditions, including those… read more here.

Keywords: hydride; iron hydride; hexagonal close; close packed ... See more keywords

Iron-catalysed alkene and heteroarene H/D exchange by reversible protonation of iron-hydride intermediates

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recommendations! Published in 2022 at "Chemical Science"

DOI: 10.1039/d2sc03802a

Abstract: C–H functionalisation reactions offer a sustainable method for molecular construction and diversification. These reactions however remain dominated by precious metal catalysis. While significant interest in iron-catalysed C–H activation reactions has emerged, the isolation, characterisation and… read more here.

Keywords: iron hydride; iron; exchange; iron catalysed ... See more keywords

Superionic iron hydride shapes ultralow-velocity zones at Earth’s core–mantle boundary

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recommendations! Published in 2024 at "Proceedings of the National Academy of Sciences of the United States of America"

DOI: 10.1073/pnas.2406386121

Abstract: Significance Recent advancements in seismology have unveiled that ULVZs are not confined solely to low-velocity zones at the CMB but also discernible within high-velocity regions, which is not well understood. Delivery of water to the… read more here.

Keywords: superionic iron; velocity zones; velocity; iron hydride ... See more keywords