Synthesis and reactivity of silyl iron hydride via Si H bond activation
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2016.10.017
Abstract: Abstract The preligand pyridine-2-amino(methyl)-dimethylsilane (1) was used to synthesize silyl iron hydride. Iron(II) hydride FeH(N(κN-C5H4N)Me(SiMe2))(PMe3)3 (2) was obtained through the reaction of 1 and Fe(PMe3)4 via the activation of one Si H bond and the… read more here.
Keywords: pme3; sime2 pme3; bond; iron hydride ... See more keywords
Hexagonal Close-packed Iron Hydride behind the Conventional Phase Diagram
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DOI: 10.1038/s41598-019-48817-7
Abstract: Hexagonal close-packed iron hydride, hcp FeH x , is absent from the conventional phase diagram of the Fe–H system, although hcp metallic Fe exists stably over extensive temperature (T) and pressure (P) conditions, including those… read more here.
Keywords: hydride; iron hydride; hexagonal close; close packed ... See more keywords
Iron-catalysed alkene and heteroarene H/D exchange by reversible protonation of iron-hydride intermediates
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DOI: 10.1039/d2sc03802a
Abstract: C–H functionalisation reactions offer a sustainable method for molecular construction and diversification. These reactions however remain dominated by precious metal catalysis. While significant interest in iron-catalysed C–H activation reactions has emerged, the isolation, characterisation and… read more here.
Keywords: iron hydride; iron; exchange; iron catalysed ... See more keywords