Construction of Ultra-Stable Ultrathin Black Phosphorus Nanodisks Hybridized with Fe3 O4 Nanoclusters and Iron (V)-Oxo Complex for Efficient Potassium Storage.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202301772
Abstract: The practical application of metalloid black phosphorus (BP) based anodes for potassium ion batteries (PIBs) is mainly impeded by its instability in air and irreversible/sluggish potassium -storage behaviors. Herein, w e purposefully conceptualize a two-dimensional… read more here.
Keywords: potassium; iron oxo; fe3 nanoclusters; potassium storage ... See more keywords
High-Valent Iron-Oxo Complexes as Dominant Species to Eliminate Pharmaceuticals and Chloride-Containing Intermediates by the Activation of Peroxymonosulfate Under Visible Irradiation
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Letters"
DOI: 10.1007/s10562-019-03047-4
Abstract: Abstract Generally, the sulfate (SO 4 · − ) and hydroxyl (HO · ) radicals are the dominant active species in most catalytic oxidation processes with peroxymonosulfate (PMS). However, the existence of various natural organic… read more here.
Keywords: iron; valent iron; high valent; iron oxo ... See more keywords
Re-investigation of an octanuclear iron-oxo complex supported by 4- butyl-pyrazolido ligands
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.07.003
Abstract: Abstract The synthesis and characterization of the octanuclear all-ferric compounds [Fe8(μ4-O)4(μ-4-R-pz)12Cl4], R = tBu (1) and nBu (2) by spectroscopic (1H NMR, UV–Vis, FTIR, 57Fe-Mossbauer) and electrochemical methods are reported along with the single crystal X-ray structure… read more here.
Keywords: investigation octanuclear; iron oxo; supported butyl; octanuclear iron ... See more keywords
Enhanced Oxidation of Organic Contaminants by Iron(II)-Activated Periodate: The Significance of High-Valent Iron-Oxo Species.
Sign Up to like & getrecommendations! Published in 2021 at "Environmental science & technology"
DOI: 10.1021/acs.est.1c00375
Abstract: Potassium periodate (PI, KIO4) was readily activated by Fe(II) under acidic conditions, resulting in the enhanced abatement of organic contaminants in 2 min, with the decay ratios of the selected pollutants even outnumbered those in… read more here.
Keywords: oxo species; organic contaminants; high valent; iron oxo ... See more keywords
Aminopolyol-Dependent Assembly of Heterometallic Lanthanide-Iron-Oxo Clusters.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03007
Abstract: Lanthanide-iron clusters usually display interesting structures and outstanding magnetic properties. However, due to the high reactivity (acidity) of the Fe3+-H2O bond and the inability to form a terminal oxo ligand, the preparation of high-nuclearity Ln-Fe… read more here.
Keywords: oxo clusters; iron; lanthanide iron; iron oxo ... See more keywords
Use of Singlet Oxygen in the Generation of a Mononuclear Nonheme Iron(IV)-Oxo Complex.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04020
Abstract: Nonheme iron(III)-superoxo intermediates are generated in the activation of dioxygen (O2) by nonheme iron(II) complexes and then converted to iron(IV)-oxo species by reacting with hydrogen donor substrates with relatively weak C-H bonds. If singlet oxygen… read more here.
Keywords: iron oxo; iron; chemistry; nonheme iron ... See more keywords
A Mononuclear Nonheme Iron(IV)-Oxo Complex of a Substituted N4Py Ligand: Effect of Ligand Field on Oxygen Atom Transfer and C-H Bond Cleavage Reactivity.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02577
Abstract: A mononuclear iron(II) complex [FeII(N4PyMe2)(OTf)](OTf)(1), supported by a new pentadentate ligand, bis(6-methylpyridin-2-yl)- N, N-bis((pyridin-2-yl)methyl)methanamine (N4PyMe2), has been isolated and characterized. Introduction of methyl groups in the 6-position of two pyridine rings makes the N4PyMe2 a… read more here.
Keywords: atom transfer; complex; iron oxo; iron ... See more keywords
Catalytic Oxidation of Water with High-Spin Iron(IV)–Oxo Species: Role of the Water Solvent
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b00568
Abstract: We use density functional theory (DFT) and ab initio molecular dynamics to study the conversion of H2O into H2O2 in water solution by the FeIVO2+ group under room-temperature and -pressure conditions. We compute the free… read more here.
Keywords: high spin; oxo species; water; iron oxo ... See more keywords
Unmasking the Iron–Oxo Bond of the [(Ligand)Fe-OIAr]2+/+ Complexes
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Society for Mass Spectrometry"
DOI: 10.1021/jasms.2c00094
Abstract: ArIO (ArI = 2-(tBuSO2)C6H4I) is an oxidant used to oxidize FeII species to their FeIV-oxo state, enabling hydrogen-atom transfer (HAT) and oxygen-atom transfer (OAT) reactions at low energy barriers. ArIO, as a ligand, generates masked… read more here.
Keywords: iron oxo; tpa; ligand; ario ... See more keywords
An investigation of ligand effects on the visible light-induced formation of porphyrin–iron(IV)-oxo intermediates
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c7nj03296j
Abstract: High-valent porphyrin–iron-oxo intermediates are the central oxidizing species in heme-containing enzymes and synthetic oxidation catalysts. In this work, we investigated a new photochemical entry to porphyrin–iron(IV)-oxo derivatives in a variety of porphyrin ligands with different… read more here.
Keywords: iron; porphyrin iron; oxo intermediates; iron oxo ... See more keywords
Oxidative dehalogenation of halophenols by high-valent nonheme iron(IV)-oxo intermediates.
Sign Up to like & getrecommendations! Published in 2022 at "Faraday discussions"
DOI: 10.1039/d1fd00064k
Abstract: Mononuclear high-valent iron(IV)-oxo intermediates are excellent oxidants towards oxygenation reactions by heme and nonheme metalloenzymes and their model systems. One of the most important functions of these intermediates in nature is to detoxify various environmental… read more here.
Keywords: iron; iron oxo; dehalogenation; oxo intermediates ... See more keywords