Shedding light on iron pentacarbonyl photochemistry through a CVD case study
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2017.06.024
Abstract: Abstract During our studies on surface engineering, we photopolymerize syngas onto silicon surfaces. XPS and TOF-SIMS analyses show that the syngas-derived oligomer covalently bonds to free silanol sites. Iron atoms appear in the coating, despite… read more here.
Keywords: photochemistry cvd; pentacarbonyl photochemistry; light iron; iron pentacarbonyl ... See more keywords
Theoretical Analysis of Fe K-Edge XANES on Iron Pentacarbonyl
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.9b03887
Abstract: Iron pentacarbonyl (Fe(CO)5) is a versatile material that is utilized as an inhibitor of flame, shows soot suppressibility, and is used as a precursor for focused electron-beam-induced deposition (FEBID). X-ray absorption near-edge structure (XANES) of… read more here.
Keywords: analysis edge; edge; geometry; iron pentacarbonyl ... See more keywords
Structure and Spectroscopy of Iron Pentacarbonyl, Fe(CO)5
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01469
Abstract: We have re-investigated the structure and vibrational spectroscopy of the iconic molecule iron pentacarbonyl, Fe(CO)5, in the solid state by neutron scattering methods. In addition to the known C2/c structure, we find that Fe(CO)5 undergoes… read more here.
Keywords: iron pentacarbonyl; spectroscopy; structure; strain ... See more keywords
Iron pentacarbonyl ligands on silver scorpionates.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06859h
Abstract: Fluorinated tris(pyrazolyl)borate supporting ligands enable the stabilization of silver(I) bonded to a neutral, organometallic Fe(CO)5 ligand. The Ag-Fe interaction in these molecules is mainly electrostatic in nature, but σ-donor and backbonding contributions between the two… read more here.
Keywords: iron pentacarbonyl; ligands silver; pentacarbonyl ligands; silver scorpionates ... See more keywords
Ultrapurification of iron pentacarbonyl by distillation techniques
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic Materials"
DOI: 10.1134/s002016851710003x
Abstract: Volatile impurities have been removed from iron pentacarbonyl of natural isotopic composition by vacuum pumping. We have examined the behavior of impurities in the course of fractional distillation of iron pentacarbonyl. As a result of… read more here.
Keywords: iron; pentacarbonyl distillation; iron pentacarbonyl; ultrapurification iron ... See more keywords