Compression Produces a Square-Planar Iron Tetracarbonyl.
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DOI: 10.1021/acs.inorgchem.2c00346
Abstract: Iron carbonyls are known to form 18-electron complexes like Fe(CO)5, Fe2(CO)9, and Fe3(CO)12 having terminal or bridged Fe-CO bonding. Based on genetic algorithm-assisted density functional theory (DFT) calculations, it is predicted that at pressures above… read more here.
Keywords: iron tetracarbonyl; square planar; chemistry; geometry ... See more keywords