Study of spin crossover in an iron(II) tris(diimine) system tuned by counter anions
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DOI: 10.1016/j.poly.2016.09.059
Abstract: Abstract Investigations of spin-crossover in an iron(II) tris(diimine) system, based on the ligands L1 (4,5-dimethy-2-(pyridine-2-yl)imidazole) and L2 (1-acetic ethyl-2-(pyridine-2-yl)-imidazole), have been presented in this paper. The methyl groups at adjacent sites to the donor atoms… read more here.
Keywords: iron tris; spin crossover; crossover iron; counter anions ... See more keywords
Iron(II) and 1,1,1-Tris(2-pyridyl)nonadecane Complex Showing an Order-Disorder-Type Structural Transition and Spin-Crossover Synchronized over Both Conformers.
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DOI: 10.1021/acs.inorgchem.9b01146
Abstract: The title compound (Me4N)[Fe{(2-py)3C- n-C18H37}(NCS)3] having a C18 chain underwent spin-crossover (SCO). There are two crystallographically independent molecules in a triclinic cell at 100 K but only one in a monoclinic cell at 300 K.… read more here.
Keywords: structural transition; spin crossover; iron tris;