Irreversible conversion of nanoporous lead(II) metal–organic framework to a nonporous coordination polymer upon thermal treatment
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DOI: 10.1016/j.poly.2018.09.009
Abstract: Abstract The reaction between 1,4-benzenedicarboxylic acid and Pb(NO3)2 in the presence of hydrogen peroxide and triethylamine with mechanochemical solid–solid and solid–gas processes results in formation of [Pb(1,4-BDC)(C2H5OH)(C2H5OH)]n (1) nanoflowers. This compound also recognized as MOF-70.… read more here.
Keywords: irreversible conversion; coordination polymer; nonporous coordination;