The importance of tetrel bonding interactions with carbon in two arrestive iso-structural Cd(ii)–Salen coordination complexes: a comprehensive DFT overview in crystal engineering
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DOI: 10.1039/d2ra07080d
Abstract: In this article, we describe the serendipitous synthesis of two remarkable iso-structural Cd(ii)–Salen complexes [L2Cd4(OAc)2(NCS)2] in the presence of H2L and NaSCN {where L = L1 (N,N′-bis(3-methoxysalicylidene)-1,2-diaminopropane) and L = L2 (N,N′-bis(3-methoxysalicylidene)-ethylenediamine) in 1 and… read more here.
Keywords: iso structural; geometry; structural salen; tetrel bonding ... See more keywords