2-Nitrobenzyl Isocyanide as a Universal Convertible Isocyanide.
Sign Up to like & getrecommendations! Published in 2017 at "Asian journal of organic chemistry"
DOI: 10.1002/ajoc.201700177
Abstract: 2-Nitrobenzyl isocyanide is reported as a universal convertible isocyanide with extensive applicability in both Ugi four-component reaction (Ugi-4CR) and Ugi-tetrazole reaction. The cleavage of this isocyanide from 17 examples in both acidic and basic conditions… read more here.
Keywords: nitrobenzyl isocyanide; isocyanide universal; universal convertible; convertible isocyanide ... See more keywords
Mixed-Isocyanide Complexes of Technetium under Steric and Electronic Control.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02730
Abstract: Reactions of the alkyl isocyanide fac-[Tc(CO)3(CNR)2Cl] complexes (2) (CNR = CNnBu or CNtBu) with the sterically encumbered isocyanide CNp-FArDarF2 [DArF = 3,5-(CF3)2C6H3] allow a selective exchange of the carbonyl ligands of 2 and the isolation… read more here.
Keywords: technetium; isocyanide; cnp fardarf2; isocyanide complexes ... See more keywords
A rare isocyanide derived from an unprecedented neutral yttrium(ii) bis(amide) complex
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00171g
Abstract: A room temperature stable complex formulated as Y(NHAr*)2 has been prepared, where Ar* = 2,6-(2,4,6-(iPr)3C6H2)C6H3, by KC8 reduction of ClY(NHAr*)2. Based on EPR evidence, Y(NHAr*)2 is an example of a d1 Y(ii) complex with significant… read more here.
Keywords: unprecedented neutral; derived unprecedented; rare isocyanide; isocyanide derived ... See more keywords
The Chemistry of Phenylimidotechnetium(V) Complexes with Isocyanides: Steric and Electronic Factors
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27238546
Abstract: Organometallic approaches are of ongoing interest for the development of novel functional 99mTc radiopharmaceuticals, while the basic organotechnetium chemistry seems frequently to be little explored. Thus, structural and reactivity studies with the long-lived isotope 99Tc… read more here.
Keywords: phenylimidotechnetium complexes; isocyanide; chemistry phenylimidotechnetium; chemistry ... See more keywords