Luminescent Mechanochromic 9-Anthryl Gold(I) Isocyanide Complex with an Emission Maximum at 900 nm after Mechanical Stimulation.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b00587
Abstract: Upon mechanical stimulation, 9-anthryl gold(I) isocyanide complex 3 exhibited a bathochromic shift of its emission color from the visible to the infrared (IR) region, which is unprecedented in its magnitude. Prior to exposure to the… read more here.
Keywords: mechanical stimulation; isocyanide complex; gold isocyanide; anthryl gold ... See more keywords
A mixed isocyanide Mn(I) complex and its reduction to a metallate.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt00634a
Abstract: A stepwise ligand exchange starting from [Mn(CO)5Br] allows the synthesis of the heteroleptic isocyanide manganese(I) complex mer,trans-[Mn(CNp-FArDArF2)3(CNtBu)2Br] (DArF = 3,5-(CF3)2C6H3, tBu = tert-butyl). Subsequent reduction gave the first heteroleptic isocyanide manganese(-1) complex, [K(18-crown-6)][Mn(CNp-FArDArF2)3(CNtBu)2], exhibiting a… read more here.
Keywords: mixed isocyanide; complex reduction; isocyanide complex; isocyanide ... See more keywords