Dithienylethene-bridged gold(I) isocyanide complexes: Synthesis, photochromism and “turn-on” fluorescent switching behavior
Sign Up to like & getrecommendations! Published in 2021 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2020.108933
Abstract: Abstract Developing novel photochromic complexes based on dithienylethene is highly desirable for potential application in the fields of photoresponsive optoelectronics. In this contribution, four novel dithienylethene-bridged gold(I) isocyanide complexes 1a-1d have been designed and prepared… read more here.
Keywords: isocyanide complexes; bridged gold; dithienylethene bridged; dithienylethene ... See more keywords
Eightfold Electrophilic Methylation of Octacyanotungstate [W(CN)8]4-/3-: Preparation of Homoleptic, Eight-Coordinate Methyl Isocyanide Complexes [W(CNMe)8]4+/5.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00326
Abstract: Homoleptic eightfold coordinated methyl isocyanide complexes of W(IV) and W(V) have been prepared for the first time. The reaction of [NBu4]4[W(CN)8] with methyl triflate (MeOTf) gives [W(CNMe)8][OTf]4. The even stronger methylating mixture of methyl fluoride… read more here.
Keywords: isocyanide complexes; octacyanotungstate preparation; methylation octacyanotungstate; eightfold electrophilic ... See more keywords
Mixed-Isocyanide Complexes of Technetium under Steric and Electronic Control.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02730
Abstract: Reactions of the alkyl isocyanide fac-[Tc(CO)3(CNR)2Cl] complexes (2) (CNR = CNnBu or CNtBu) with the sterically encumbered isocyanide CNp-FArDarF2 [DArF = 3,5-(CF3)2C6H3] allow a selective exchange of the carbonyl ligands of 2 and the isolation… read more here.
Keywords: technetium; isocyanide; cnp fardarf2; isocyanide complexes ... See more keywords
Formation and Characterization of Homoleptic Thorium Isocyanide Complexes.
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DOI: 10.1021/acs.inorgchem.7b00196
Abstract: Homoleptic thorium isocyanide complexes have been prepared via the reactions of laser-ablated thorium atoms and (CN)2 in a cryogenic matrix, and the structures of the products were characterized by infrared spectroscopy and theoretical calculations. Thorium… read more here.
Keywords: isocyanide complexes; homoleptic thorium; thorium; geometry ... See more keywords
Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide
Sign Up to like & getrecommendations! Published in 2018 at "Russian Journal of General Chemistry"
DOI: 10.1134/s1070363218110166
Abstract: Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the… read more here.
Keywords: toluenesulfonyl hydrazide; isocyanide complexes; carbonyl isocyanide; reaction toluenesulfonyl ... See more keywords