Isolated Molybdenum(VI) and Tungsten(VI) Oxide Species on Partly Dehydroxylated Silica: A Computational Perspective
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.9b09586
Abstract: Although silica-supported molybdenum and tungsten oxide systems are widely used in catalysis, the nature of the surface metal oxide species is still not fully recognized. In this work, comprehensiv... read more here.
Keywords: isolated molybdenum; species partly; oxide species; molybdenum tungsten ... See more keywords
Isolated molybdenum-based microporous POMs for selective adsorption of gases.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00134a
Abstract: Dodecanuclear, icosanuclear and octanuclear porous MOF-like POM materials [MoV12O12(μ2-O)4(μ3-O)12(Htrz)4(trz)4]·nH2O (n = 22, 1; n = 92, 2; Htrz = 1H-1,2,3-triazole), [MoV8O8(μ2-O)12(Htrz)8]½·[MoV12O12(μ2-O)4(μ3-O)12(Htrz)4(trz)4]·44H2O (3), and [MoV8O8(μ2-O)12(Htrz)8]·62H2O (4) have been obtained and well characterized. Higher Mo12 agglomerates have… read more here.
Keywords: adsorption; htrz; isolated molybdenum; based microporous ... See more keywords