Isolation of base stabilized fluoroborylene and its radical cation.
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DOI: 10.1039/c9dt01899a
Abstract: Herein, we report the synthesis and characterization of the metal free low valent fluoroborylene [(Me-cAAC)2BF] (1) stabilized by cyclic (alkyl)(amino) carbene (cAAC). The fluoroborylene 1 is obtained by the reductive defluorination of Me-cAAC:BF3 with 2.0… read more here.
Keywords: cation; isolation base; stabilized fluoroborylene; radical cation ... See more keywords