Site Isolation in Metal-Organic Layers Enhances Photoredox Gold Catalysis.
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DOI: 10.1021/jacs.2c03062
Abstract: Herein, we report the synthesis of a metal-organic layer, Hf-Ru-Au, containing Ru(bipyridine)32+-type photosensitizers and (phosphine)-AuCl catalysts for photoredox Au-catalyzed cross-coupling of allenoates, alkenes, or alkynes with aryldiazonium salts to afford furanone, tetrahydrofuran, or aryl alkyne… read more here.
Keywords: site isolation; isolation metal; metal organic;