Shifting Target Reaction from Oxygen Reduction to Superoxide Disproportionation by Tuning Isomeric Configuration of Quinone Derivative as Redox Mediator for Lithium-Oxygen Batteries.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c22621
Abstract: Quinones having a fully conjugated cyclic dione structure have been used as redox mediators in electrochemistry. 2,5-Ditert-butyl-1,4-benzoquinone (DBBQ or DB-p-BQ) as a para-quinone derivative is one of the representative discharge redox mediators for facilitating the… read more here.
Keywords: isomeric configuration; reaction; redox; oxygen ... See more keywords
Boosting the photocatalytic performance via isomeric configuration design in covalent organic frameworks.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04935j
Abstract: Two COFs (BT-COF1 and BT-COF2) with isomeric configuration were reported. Compared with BT-COF1, BT-COF2 with the narrower bandgap, smaller resistance and more evident charge transfer property exhibits superior catalytic performance in the photooxidation of sulfides. read more here.
Keywords: configuration; isomeric configuration; performance via; photocatalytic performance ... See more keywords