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   Articles with "isomerism" as a keyword



Isomerism in Molecular Metal Carbonyl Clusters

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recommendations! Published in 2024 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.202400220

Abstract: The present microreview focuses on different typologies of isomerism documented along the years for metal carbonyl clusters (MCCs), and outlines their analogies to other classes of ligand‐protected molecular clusters and nanoclusters. Isomerism in molecular MCCs… read more here.

Keywords: isomerism; metal; isomerism molecular; metal carbonyl ... See more keywords

Clinical implications of airway anomalies and stenosis in patients with heterotaxy syndrome

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recommendations! Published in 2022 at "Pediatric Pulmonology"

DOI: 10.1002/ppul.25981

Abstract: In heterotaxy syndrome, bronchopulmonary situs usually reflects atrial situs, resulting in either right (RAI) or left atrial isomerism (LAI). This study determines airway anomalies and its implications in patients with heterotaxy. This retrospective study included… read more here.

Keywords: isomerism; patients heterotaxy; anomalies stenosis; airway anomalies ... See more keywords

Thiazole inhibitors of α-glucosidase: Positional isomerism modulates selectivity, enzyme binding and potency of inhibition.

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recommendations! Published in 2022 at "Computational biology and chemistry"

DOI: 10.1016/j.compbiolchem.2022.107647

Abstract: Isomerism plays a key role in determining potency, selectivity and type of inhibition exhibited by enzyme inhibitors. We present 20 new benzylidene-hydrazinyl-thiazole inhibitors of α-glucosidase featuring positional isomerism of the methyl group at 3 and… read more here.

Keywords: enzyme; thiazole inhibitors; selectivity; inhibition ... See more keywords

A potential case of the rare Cluster Core Isomerism for phosphido-bridged Pt3 units suggested by DFT calculations

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recommendations! Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2017.09.068

Abstract: Abstract Triangular platinum clusters with phosphido bridging ligands and 44 valence electrons may adopt two structural types with either an equilateral or isosceles Pt 3 triangle, hence with a closed or an open ring formulation… read more here.

Keywords: rare cluster; core isomerism; cluster core; isomerism ... See more keywords

Laparoscopic sleeve gastrectomy in polysplenia syndrome/left isomerism: A case report

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recommendations! Published in 2020 at "International Journal of Surgery Case Reports"

DOI: 10.1016/j.ijscr.2020.09.079

Abstract: Highlights • A case of Polysplenia Syndrome (PSP) undergoing laparoscopic sleeve gastrectomy.• It is a type of heterotaxy syndrome where there are multiple spleens congenitally, with left sided isomerism.• The patient was not a known… read more here.

Keywords: laparoscopic sleeve; sleeve gastrectomy; case; polysplenia syndrome ... See more keywords

Homozygous variants in the GDF1 gene related to recurrent right isomerism and complex CHD in two Indian families.

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recommendations! Published in 2022 at "Cardiology in the young"

DOI: 10.1017/s1047951122001056

Abstract: Disorders of laterality are often associated with complex CHD. There is considerable debate about the appropriate terminology to describe these conditions. As our understanding of the genetic basis of these disorders improves, it is likely… read more here.

Keywords: isomerism; complex chd; gdf1 gene; variants gdf1 ... See more keywords

Dithiophosphonate-Protected Eight-Electron Superatomic Ag21 Nanocluster: Synthesis, Isomerism, Luminescence, and Catalytic Activity.

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recommendations! Published in 2024 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.4c02062

Abstract: The structure-property relationship considering isomerism-tuned photoluminescence and efficient catalytic activity of silver nanoclusters (NCs) is exclusive. Asymmetrical dithiophosphonate NH4[S2P(OR)(p-C6H4OCH3)] ligated first atomically precise silver NCs [Ag21{S2P(OR)(p-C6H4OCH3)}12]PF6 {where, R = nPr (1), Et (2)} were established… read more here.

Keywords: spectroscopy; eight electron; isomerism; catalytic activity ... See more keywords

Equivalent Atrop- and Positional Isomerism in Styrene Derivatives Prepared by Enantioselective 1,3-Diarylation.

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recommendations! Published in 2025 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.5c10118

Abstract: Isomerism, the ability of a single set of atoms within a molecule to exist in different three-dimensional spatial arrangements connecting through distinct bonding networks, gives rise to distinct physical, chemical, and biological properties from a… read more here.

Keywords: isomerism styrene; positional isomerism; atrop positional; isomerism ... See more keywords

Unprecedented Energy Storage in Metal-Organic Complexes via Constitutional Isomerism

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recommendations! Published in 2023 at "Chemical Science"

DOI: 10.1039/d3sc01692g

Abstract: The essence of any electrochemical system is engraved in their electrical double layer (EDL), and we report its unprecedented reorganization by the structural isomerism of molecules with a direct consequence... read more here.

Keywords: unprecedented energy; isomerism; organic complexes; storage metal ... See more keywords

Long-term outcome of patients with right atrial isomerism after common atrioventricular valve plasty†

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recommendations! Published in 2017 at "European Journal of Cardio-Thoracic Surgery"

DOI: 10.1093/ejcts/ezx001

Abstract: OBJECTIVES To review long-term outcomes of patients with right atrial (RA) isomerism who underwent common atrioventricular valve (CAVV) plasty. METHODS We retrospectively analysed 59 patients with RA isomerism operated on between January 2004 and April… read more here.

Keywords: isomerism; group bcps; cavv plasty; plasty ... See more keywords

Autopsy findings of a child with left atrial isomerism associated with pulmonary agenesis

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recommendations! Published in 2018 at "Jornal Brasileiro De Patologia E Medicina Laboratorial"

DOI: 10.5935/1676-2444.20180020

Abstract: Isomerism is a rare laterality defect. Our aim was to describe the autopsy findings of a child with left atrial isomerism (LAI) and pulmonary agenesis (PA), an association still not described in the literature. Fetal… read more here.

Keywords: agenesis; autopsy findings; autopsy; findings child ... See more keywords