Oxidation of [Ge9{Si(SiMe3)3}3]- with LnI3 (Ln = Eu, Sm, Yb): Isomerism of Metalloid Germanium Clusters.
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DOI: 10.1021/acs.inorgchem.2c01501
Abstract: The oxidation of K[Ge9(Hyp)3] (Hyp = Si(SiMe3)3) with lanthanide triiodides LnI3 (Ln = Eu, Sm, Yb) leads to the formation of novel clusters with a Ge18-core isolated as a co-crystallizate of Ge*18(Hyp)6 (1a) and Ge18(Hyp)5(Si(SiMe3)2)(SiMe3)… read more here.
Keywords: hyp; oxidation ge9; sime3; isomerism metalloid ... See more keywords