Remote Functionalization by Pd-Catalyzed Isomerization of Alkynyl Alcohols
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DOI: 10.1021/jacs.4c05136
Abstract: In recent years, progress has been made in the development of catalytic methods that allow remote functionalizations based on alkene isomerization. In contrast, protocols based on alkyne isomerization are comparatively rare. Herein, we report a… read more here.
Keywords: remote functionalization; alkynyl alcohols; isomerization alkynyl; isomerization ... See more keywords
The Pd(0) and Pd(ii) cocatalyzed isomerization of alkynyl epoxides to furans: a mechanistic investigation using DFT calculations.
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DOI: 10.1039/d0dt00965b
Abstract: The conversion of alkynyl epoxides to furans is an unusual tandem catalytic process in which two different oxidation states of palladium are employed. In this study, we used density functional theory calculations to establish the… read more here.
Keywords: alkynyl epoxides; epoxides furans; isomerization alkynyl; cocatalyzed isomerization ... See more keywords