Photocatalyzed Diastereoselective Isomerization of Cinnamyl Chlorides to Cyclopropanes.
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DOI: 10.1021/jacs.0c00147
Abstract: Endergonic isomerizations are thermodynamically unfavored processes that are difficult to realize under thermal conditions. We report a photocatalytic diastereoselective isomerization of acyclic cinnamyl chlorides to strained cyclopropanes. Quantum mechanical calculations (uM06-2X and DLPNO), including TD-DFT… read more here.
Keywords: cinnamyl chlorides; cinnamyl; photocatalyzed diastereoselective; diastereoselective isomerization ... See more keywords