Rhodium-Catalyzed Enantioselective Isomerization of Secondary Allylic Alcohols.
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DOI: 10.1021/jacs.7b01096
Abstract: The first catalytic enantioselective isomerization of secondary allylic alcohols to access ketones with a α-tertiary stereocenter is presented. The racemic allylic alcohol substrates can be converted to the enantioenriched ketone products in a stereoconvergent fashion.… read more here.
Keywords: enantioselective isomerization; rhodium catalyzed; allylic alcohols; isomerization secondary ... See more keywords