Mechanistic Studies of Pd(II)-Catalyzed E/Z Isomerization of Unactivated Alkenes: Evidence for a Monometallic Nucleopalladation Pathway.
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DOI: 10.1021/acscatal.1c00783
Abstract: Pd(II)-catalyzed E/Z isomerization of alkenes is a common process-yet its mechanism remains largely uncharacterized, particularly with non-conjugated alkenes. In this work, the mechanism of Pd(II)-catalyzed E/Z isomerization of unactivated olefins containing an aminoquinoline-based amide directing… read more here.
Keywords: monometallic nucleopalladation; isomerization unactivated; isomerization; catalyzed isomerization ... See more keywords