Development of Enantioselective Lithium-Isothiourea-Boronate–Catalyzed Matteson Homologations
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DOI: 10.1055/a-2099-6557
Abstract: Our group’s discovery of lithium-isothiourea-boronate–catalyzed Matteson homologations is chronicled. Chiral thiourea dual–hydrogen bond donors were initially found to promote enantioselective dichloromethyl boronate rearrangements, albeit with poor reproducibility. Systematic investigations of the fate of the thiourea… read more here.
Keywords: boronate; lithium; boronate catalyzed; isothiourea boronate ... See more keywords