Isotopically-Directed Symmetry Breaking and Enantioenrichment in Attrition-Enhanced Deracemization.
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DOI: 10.1021/jacs.9b11422
Abstract: TThe evolution of homochirality via attrition-enhanced deracemization (AED) of enantiomorphic solids is carried out using molecules that differ only in the isotopic composition of a phenyl group positioned remote from the chiral center. Enanti-oenrichment consistently… read more here.
Keywords: attrition enhanced; enhanced deracemization; deracemization; isotopically directed ... See more keywords