High-Resolution ENDOR Spectroscopy Combined with Quantum Chemical Calculations Reveals the Structure of Nitrogenase Janus Intermediate E4(4H).
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DOI: 10.1021/jacs.9b04474
Abstract: We have shown that the key state in N2 reduction to two NH3 molecules by the enzyme nitrogenase is E4(4H), the "Janus" intermediate, which has accumulated four [e-/H+] and is poised to undergo reductive elimination… read more here.
Keywords: janus intermediate; endor; nitrogenase janus; spectroscopy ... See more keywords