Synthesis of Polypeptoid-Polycaprolactone-Polytetrahydrofuran Heterograft Molecular Polymer Brushes via a Combination of Janus Polymerization and ROMP.
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201800905
Abstract: Janus polymerization is a novel and efficient way to synthesize diblock and multiblock copolymers in one step by using Lu(OTf)3 and propylene epoxide as a catalytic system. By modifying the epoxide initiator, which is located… read more here.
Keywords: polymerization; janus polymerization; polymer brushes; heterograft molecular ... See more keywords
3-Miktoarm Star Terpolymers via Janus Polymerization: One-Step Synthesis and Self-Assembly
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DOI: 10.1021/acs.macromol.8b00949
Abstract: Janus polymerization combines cationic and anionic polymerizations into the two ends of a single growing chain and presents a novel pathway to produce topologically defined polymers. In this contribution, we report a one-step synthesis of… read more here.
Keywords: janus polymerization; star; self assembly; one step ... See more keywords
Properties of Electrospun Nanofibers of Multi-Block Copolymers of [Poly-ε-caprolactone-b-poly(tetrahydrofuran-co-ε-caprolactone)]m Synthesized by Janus Polymerization
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DOI: 10.3390/polym9110559
Abstract: Novel biodegradable multiblock copolymers of [PCL-b-P(THF-co-CL)]m with PCL fractions of 53.3 and 88.4 wt % were prepared by Janus polymerization of ε-caprolactone (CL) and tetrahydrofuran (THF). Their electrospun mats were obtained with optimized parameters containing… read more here.
Keywords: electrospun nanofibers; janus polymerization; caprolactone; properties electrospun ... See more keywords