Juniperanol: First total synthesis and evaluation in Type 2 Diabetes disease.
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DOI: 10.1016/j.bioorg.2019.103243
Abstract: The first total synthesis of juniperanol, the tricyclic sesquiterpenoid enantiomer of α-cedrol is described. The synthesis relies on stereoselective gold-catalyzed Ohloff-type propargylic ester rearrangement performed on a 10 g scale, and a carbocationic cascade in the… read more here.
Keywords: juniperanol; juniperanol first; first total; total synthesis ... See more keywords