Enhancement of Propadiene/Propylene Separation Performance of Metal-Organic Frameworks by an Amine-Functionalized Strategy.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03276
Abstract: Here, a hexanuclear Co6(μ3-OH)6 cluster-based metal-organic framework (MOF), [Co6(μ3-OH)6(BTB)2(bpy)3]n (JXNU-15) (bpy = 4,4'-bipyridine), with the 1,3,5-tri(4-carboxyphenyl)benzene (BTB3-) ligand was synthesized for the challenging propadiene/propylene separation. The combination of a large pore volume and a suitable… read more here.
Keywords: jxnu; separation performance; propadiene propylene; amine functionalized ... See more keywords
Boosting the C2H2/CO2 Separation Performance of Metal-Organic Frameworks through Fluorine Substitution.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00954
Abstract: A pair of metal-organic frameworks (MOFs) of JXNU-15 (formulated as [Co6(μ3-OH)6(BTB)2(BPY)3]n, BTB3- = benzene-1,3,5-tribenzoate and BPY = 4,4'-bipyridine) and its fluorinated JXNU-15(F) ([Co6(μ3-OH)6(SFBTB)2(BPY)3]n) based on the fluorous 1,3,5-tri(3,5-bifluoro-4-carboxyphenyl)benzene (SFBTB3-) ligands were presented. The detailed comparisons… read more here.
Keywords: jxnu; c2h2 co2; co2 separation; separation performance ... See more keywords