Reductive C-O Cleavage of Ethereal Solvents and 18-Crown-6 in Ln(NR2)3/KC8 Reactions (R = SiMe3).
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00689
Abstract: The high reactivity accessible from the reduction of the tris(amide) complexes Ln(NR2)3 (R = SiMe3) with potassium graphite in the presence of a variety of ethers is demonstrated by crystal structures of six different types… read more here.
Keywords: cleavage; kc8 reactions; kc8; nr2 kc8 ... See more keywords
Isolable zero-valent Ditin(0) and Diplumbum(0) complexes
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DOI: 10.1038/s41467-025-57568-1
Abstract: Although complexes with monatomic zero-valent main group centers have been reported, diatomic zero-valent complexes are extremely rare and all previously reported examples were stabilized by either carbene or silylene ligands. Here, we present the isolation… read more here.
Keywords: valent; kc8; zero valent; main group ... See more keywords