Synergetic Catalysis of Copper and Iron in Oxidation of Reduced Keggin Heteropolytungstates by Dioxygen.
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DOI: 10.1021/acs.inorgchem.7b02506
Abstract: Polyoxometalates (POMs) and in particularly Keggin heteropolytungstates are much studied and commercially important catalysts for dioxygen-based oxidation processes. The rate-limiting step in many POM-catalyzed O2-based oxidations is reoxidation of the reduced POM by O2. We… read more here.
Keywords: keggin heteropolytungstates; reduced keggin; copper iron; oxidation ... See more keywords