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Published in 2018 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2018.08.004
Abstract: Abstract Reaction mechanism corresponding to reduction of NO to N2 by hydroxylammonium chloride (NH2OH⋅HCl) catalyzed by a ruthenium–substituted Keggin-type polyoxometalates (POMs) has been studied by using density functional theory (DFT) method with the M06L functional.…
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Keywords:
reduction;
catalyzed ruthenium;
ruthenium substituted;
keggin type ... See more keywords
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Published in 2022 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2022.04.006
Abstract: The incorporation of polyoxometalates (POMs) in metal-organic frameworks (MOFs) with host-guest structure have proven to be effective strategy to rational design of heterogeneous catalysis. In this study, the Keggin-type POM@MIL-101(Cr) composite catalysts (PMo12, PW12 and…
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Keywords:
siw12;
mil 101;
keggin type;
fixation reaction ... See more keywords
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Published in 2019 at "Journal of Photochemistry and Photobiology A: Chemistry"
DOI: 10.1016/j.jphotochem.2018.10.031
Abstract: Abstract Heteropolyacid supported ZrO2 nanocomposites has been prepared through wet impregnation method with the intention to improve the photodegradation performance under UV light. The material consist of mixed monoclinic and cubic ZrO2 phase and orthorhombic…
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Keywords:
microscopy;
spectroscopy;
keggin type;
zirconia ... See more keywords
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Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.01.036
Abstract: Abstract In this work, a novel organic–inorganic nanohybrid compound, namely [Cu{(HOCH2CH2)2NCS2}2]3[PW12O40] (1), was prepared via the reaction of a copper(II) dithiocarbamate complex, Cu{(HOCH2CH2)2NCS2}2, and a Keggin-type heteropolyacid, H3PW12O40. The nanohybrid 1 was characterized by FT-IR,…
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Keywords:
organic inorganic;
keggin type;
dithiocarbamate complex;
structure ... See more keywords
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Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c03214
Abstract: The reaction of mid to late lanthanide ions with the N,N′-dimethyl-N,N′-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylene-diamine organic ligand and monolacunary Keggin type [α-SiW11O39]8– anion affords a series of isostructural compounds, namely, K5[LnIII(α-SiW11O39)(C20H22Br2N2O4)]·14H2O (1-Ln, Ln = Sm to Lu). The molecular…
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Keywords:
keggin type;
magnetic relaxation;
relaxation;
type ... See more keywords
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Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03769
Abstract: Polyoxometalates (POMs) represent a promising class of molecular electron reservoirs. However, their multielectron reduction gives rise to intricate physical-chemical phenomena that must be fully understood for their future use in energy-storage devices. Herein, we show…
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Keywords:
keggin type;
metal bonds;
six electron;
metal ... See more keywords
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Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00667
Abstract: Three proton-conductive decorated Keggin-type clusters, {[Cu(debpdc)(H2O)3][Cu(debpdc)(H2O)Cl][PMo12O40]} ·2CH3OH ·1.5CH3CN ·3H2O (1), {[Cu(H2bpdc)(H2O)2Cl0.5]2[PW12O40]}·10H2O (2), and {[Cu(H2bpdc)(H2O)2.5]2[SiW12O40]}·10H2O (3) (where debpdc is diethyl 2,2'-bipyridine-4,4'-dicarboxylate and H2bpdc is 2,2'-bipyridine-4,4'-dicarboxylic acid), were synthesized through electrostatic and coordination interactions between Keggin-type anions…
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Keywords:
type clusters;
complex moieties;
keggin type;
proton conductive ... See more keywords
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Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00714d
Abstract: To achieve improved properties such as lower biotoxicity and better biocatalytic performances, the preparation of low oxidation state (+3) vanadium (V)-organic framework compounds (VIII-OFCs) is an important research area. Additionally, the incorporation of VIII-OFCs into…
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Keywords:
viii;
synthetic strategy;
keggin type;
redox based ... See more keywords
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Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00312f
Abstract: Two kinds of organic-inorganic 3d-4f heterometal hybrids based on plenary α-Keggin-type germanotungstates [Cu2(H2O)3(PA)3] [Ln0.5Na0.5Cu2(H2O)12(PA)3][α-GeW12O40]·5H2O [Ln = La3+ (1), Ce3+ (2)] and [Cu2(H2O)2(PA)3][Cu(PA)2][Ln(H2O)7][α-GeW12O40]·7H2O [Ln = Tb3+ (3), Dy3+ (4), HPA = 2-picolinic acid] were prepared via…
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Keywords:
organic inorganic;
h2o;
keggin type;
cu2 h2o ... See more keywords
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Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00499a
Abstract: Bi3+ and Pb2+ uptake by a monolacunary Keggin-type [PW11O39]7- anion leads to the formation of [PW11O39Bi]4- and [PW11O39Pb]5- complexes with a stereochemically active lone pair at the incorporated heterometal. The two complexes were isolated as…
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Keywords:
type polyoxometalate;
keggin type;
experimental theoretical;
iii experimental ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05904e
Abstract: A novel supramolecular complex Li3Cl[(HPW12O40)(H24C12O6)3(CH3CN)2] {CR-PW12} was confirmed first to apply as a sulfur host in lithium-sulfur batteries. The {CR-PW12}@S cathode exhibits a reversible capacity of 1120 mA h g-1 at 1.0 C and excellent…
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Keywords:
keggin type;
lithium sulfur;
sulfur;
type polyoxometalate ... See more keywords