Magnesium and zinc complexes bearing NNO-tridentate ketiminate ligands: synthesis, structures and catalysis in the ring-opening polymerization of lactides.
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DOI: 10.1039/c8dt00888d
Abstract: A series of magnesium and zinc complexes, [(L1-3)2M2(μ-OBn)2] (M = Mg (1-3), Zn (4-6)), have been synthesized by the reaction of NNO-tridentate ketiminate ligands (L1-3-H) and a stoichiometric amount of MgnBu2 (or ZnEt2) and BnOH.… read more here.
Keywords: ring opening; polymerization; opening polymerization; ketiminate ligands ... See more keywords
Synthesis, Structure and DFT Calculation of Bi- and Tridentate Ketiminate Ligands Assisted Aluminum Complexes: Potential Catalyst for Styrene Oxide-CO2 Cycloaddition Reaction
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DOI: 10.1039/d5nj03282b
Abstract: A series of ketiminate ligands, L1H-L4H are first synthesized by coupling of benzoylacetone with phenylhydrazine, 2-methoxy-5-methylaniline, (+/-)-tetrahydrofurfurylamine, N-(2-aminoethyl)-piperidine, respectively, in adequate yields. Deprotonation of L1H-L4H with one equivalent of AlMe3... read more here.
Keywords: structure dft; calculation tridentate; synthesis structure; dft calculation ... See more keywords