Substrate-controlled product divergence in the reaction of α-fluoro-β-ketoamides with arynes.
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DOI: 10.1039/d2cc04657a
Abstract: An interesting substrate-controlled reactivity switch has been observed in the reaction of α-fluoro-β-ketoamides with arynes. The reaction of secondary α-fluoro-β-ketoamides with arynes provided access to α-aryl-α-fluoroacetamides through an arylation/deacylation sequence. Interestingly, the reaction of tertiary… read more here.
Keywords: reaction; reaction fluoro; ketoamides arynes; fluoro ketoamides ... See more keywords