Organocatalytic Enantioselective γ-Position-Selective Mannich Reactions of β-Ketocarbonyl Derivatives
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DOI: 10.1021/acs.orglett.2c02433
Abstract: Catalytic asymmetric Mannich reactions of β-ketocarbonyl derivatives (such as β-ketoesters and (2-oxopropyl)phosphonate), resulting in the formation of a C–C bond at the γ-position of the β-ketocarbonyl derivatives with high enantioselectivities, are reported. The bond formation… read more here.
Keywords: reactions ketocarbonyl; ketocarbonyl derivatives; organocatalytic enantioselective; enantioselective position ... See more keywords