DFT study on selective autocatalyzed α-alkylation of ketones with alcohols
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.03.033
Abstract: Abstract Base-promoted transition-metal-free α -alkylation of ketones with alcohols is an efficient, practical, and green method for the formation of new C C bonds. Here, we present a DFT study on NaOH/KOH-promoted selective autocatalyzed α… read more here.
Keywords: alkylation ketones; dft study; ketones alcohols; selective autocatalyzed ... See more keywords
Copper-catalyzed multiple oxidation and cycloaddition of aryl-alkyl ketones (alcohols) for the synthesis of 4-acyl- and 4-diketo-1,2,3-triazoles.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06477k
Abstract: A Cu/TEMPO-catalyzed tandem multiple oxidative dehydrogenation and cycloaddition has been developed, which affords 4-acyl-1,2,3-triazoles and 4-diketo-1,2,3-triazoles from readily-available aryl-alkyl ketones (or alcohols) and different organic azides. Moreover, the reaction used environmentally friendly dimethyl carbonate (DMC)… read more here.
Keywords: aryl alkyl; diketo triazoles; copper catalyzed; alkyl ketones ... See more keywords
Immobilizing a homogeneous manganese catalyst into MOF pores for α-alkylation of methylene ketones with alcohols.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02629e
Abstract: Herein, for the first time, a metal-organic framework (MOF) is reported as a catalyst for α-alkylation of ketones with alcohols. Using an encapsulation strategy via nano-confinement of a homogeneous Mn-phenanthroline complex into MOF pores, functionalized… read more here.
Keywords: mof pores; manganese catalyst; mof; homogeneous manganese ... See more keywords