Alkylation of Ketones Catalyzed by Bifunctional Iron Complexes: From Mechanistic Understanding to Application
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201701241
Abstract: Cyclopentadienone iron dicarbonyl complexes were applied in the alkylation of ketones with various aliphatic and aromatic ketones and alcohols via the borrowing hydrogen strategy in mild reaction conditions. DFT calculations and experimental works highlight the… read more here.
Keywords: alkylation ketones; ketones catalyzed; catalyzed bifunctional; iron ... See more keywords
Hydrosilylation of Aldehydes and Ketones Catalyzed by a 2-Iminopyrrolyl Alkyl-Manganese(II) Complex.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03621
Abstract: A well-defined and very active single-component manganese(II) catalyst system for the hydrosilylation of aldehydes and ketones is presented. First, the reaction of 5-(2,4,6-iPr3C6H2)-2-[N-(2,6-iPr2C6H3)formimino]pyrrolyl potassium (KL) and [MnCl2(Py)2] afforded the binuclear 2-iminopyrrolyl manganese(II) pyridine chloride complex… read more here.
Keywords: aldehydes ketones; spectroscopy; catalyzed iminopyrrolyl; hydrosilylation aldehydes ... See more keywords
Asymmetric Borylative Propargylation of Ketones Catalyzed by a Copper(I) Complex.
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DOI: 10.1021/acs.orglett.8b03912
Abstract: A copper(I)-catalyzed asymmetric borylative propargylation of simple ketones was disclosed. Additive NaBARF was found to be pivotal to achieve excellent enantioselectivity. This reaction enjoyed advantages of broad substrate scope, good tolerance of functional groups, high… read more here.
Keywords: propargylation ketones; copper; ketones catalyzed; asymmetric borylative ... See more keywords
Hydrosilylation of Aromatic Aldehydes and Ketones Catalyzed by Mono- and Tri-Nuclear Platinum(0) Complexes
Sign Up to like & getrecommendations! Published in 2018 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1246/bcsj.20170397
Abstract: Hydrosilylation of aromatic aldehydes and acetophenone with H2SiPh2 was studied by using Pt complexes as the catalyst. Reaction of aromatic aldehydes, such as PhCHO, 4-FC6H4CHO, 4-MeC6H4CHO and 4-CF3C6H4CHO with H2SiPh2 in the presence of [Pt(PPh3)3]… read more here.
Keywords: hydrosilylation aromatic; h2siph2; aldehydes ketones; ketones catalyzed ... See more keywords