Stereoselective Oxidative Mannich Reaction of Ketones with Dihydrodibenzo-oxazepines via a Merger of Photoredox-/Electro-catalysis with Organocatalysis.
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DOI: 10.1002/cssc.202200415
Abstract: An enantio- and diastereoselective sp 3 -sp 3 coupling of acyclic/cyclic ketones with dihydrodibenzo-oxazepines has been developed by merging visible light photo-redox- or electro-catalysis with organocatalysis. This approach parallelly utilizes Eosin Y or graphite electrodes… read more here.
Keywords: dihydrodibenzo oxazepines; reaction ketones; catalysis organocatalysis; electro catalysis ... See more keywords