Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b03720
Abstract: Herein we report the manganese-catalyzed C–C bond-forming reactions via α-alkylation of ketones, amides, and esters, using primary alcohols. β-Alkylation of secondary alcohols by primary alcohols to obtain α-alkylated ketones is also reported. The reactions are… read more here.
Keywords: manganese catalyzed; catalyzed alkylation; esters amides; alkylation ... See more keywords
Hydrogenation of Ketones and Esters Catalyzed by Pd/C‒SiO2
Sign Up to like & getrecommendations! Published in 2018 at "Russian Journal of General Chemistry"
DOI: 10.1134/s1070363218020032
Abstract: Hydrogenation of unsaturated ketones and esters with molecular hydrogen on the 5%Pd/C‒SiO2 heterogeneous catalyst has been studied. The reaction direction and yield are determined by the starting compounds structure. Hydrogenation of unsaturated ketones containing phenyl… read more here.
Keywords: ketones esters; catalyzed sio2; hydrogenation; hydrogenation unsaturated ... See more keywords