Transition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds.
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DOI: 10.1021/acs.orglett.7b01474
Abstract: We report a transition-metal-free coupling of aldehydes and ketones with geminal bis(boron) building blocks which provides the coupled, homologated carbonyl compound upon oxidation. This reaction not only extends an alkyl chain containing a carbonyl group,… read more here.
Keywords: coupling aldehydes; transition metal; aldehydes ketones; ketones geminal ... See more keywords