Experimental and theoretical assessment of the mechanism and site requirements for ketonization of carboxylic acids on oxides
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DOI: 10.1016/j.jcat.2016.11.006
Abstract: Abstract Ketonization of carboxylic acids removes O-atoms and forms new C C bonds, thus providing routes from sustainable carbon feedstocks to fuels and chemicals. The elementary steps involved and their kinetic relevance, as well as… read more here.
Keywords: tio2; ketonization carboxylic; carboxylic acids; acid base ... See more keywords
Experimental and Theoretical Evidence for the Reactivity of Bound Intermediates in Ketonization of Carboxylic Acids and Consequences of Acid–Base Properties of Oxide Catalysts
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b05987
Abstract: Ketonization of carboxylic acids on metal oxides enables oxygen removal and the formation of new C–C bonds for increasing the energy density and chemical value of biomass-derived streams. Information about the surface coverages and reactivity… read more here.
Keywords: ketonization; ketonization carboxylic; carboxylic acids; base properties ... See more keywords