Theoretical and experimental study demonstrates kinetic control in chalcone-flavanone transformation of naphthalene derivatives
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.12.078
Abstract: Abstract The condensation of 1′-hydroxy-2′-acetonaphthone with 1- or 2-naphthaldehyde produced the corresponding stable chalcones: C1 or C2. However, the condensation product of either naphthaldehyde with 2′-hydroxy-1′-acetonaphthone yielded chalcones that convert to flavanones- F1 and F2-… read more here.
Keywords: control chalcone; experimental study; theoretical experimental; demonstrates kinetic ... See more keywords
Kinetic Control over CdS Nanocrystal Nucleation Using a Library of Thiocarbonates, Thiocarbamates, and Thioureas
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.7b02861
Abstract: We report a family of substituted thiocarbonates, thiocarbamates, and thioureas and their reaction with cadmium oleate at 180–240 °C to form zincblende CdS nanocrystals (d = 2.2–5.9 nm). To monitor the kinetics of CdS formation… read more here.
Keywords: thiocarbamates thioureas; nucleation; control cds; kinetic control ... See more keywords
Kinetic Control in the Alignment of Polar π-Conjugated Molecules inside Carbon Nanotubes
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b05455
Abstract: Dispersion-corrected density functional theory (DFT) calculations analyze potential energy surfaces (PESs) for the insertion of a certain polarized π-conjugated molecule, p-(dimethylamino)-p′-nitro... read more here.
Keywords: polar conjugated; alignment polar; control alignment; kinetic control ... See more keywords
Enzyme-Induced Kinetic Control of Peptide–Polymer Micelle Morphology
Sign Up to like & getrecommendations! Published in 2019 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00887
Abstract: In this paper, experiment and simulation were combined to provide a view of the molecular rearrangements underlying the equilibrium and nonequilibrium transitions occurring in stimuli-responsive bl... read more here.
Keywords: polymer micelle; enzyme induced; control peptide; induced kinetic ... See more keywords
Energetic and Kinetic Control Aspects to Explain the Performances and Elucidate the Mechanisms of Oriented Membrane Processes for Extraction and Recovery of Glycerol Compound
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c05637
Abstract: Facilitated extraction membrane processes present a promising technology to replace conventional methods of producing and purifying glycerol. They offer green, ecofriendly, and sustainable platform... read more here.
Keywords: membrane processes; glycerol; energetic kinetic; kinetic control ... See more keywords
Kinetic Control of Parallel versus Antiparallel Amyloid Aggregation via Shape of the Growing Aggregate
Sign Up to like & getrecommendations! Published in 2019 at "Scientific Reports"
DOI: 10.1038/s41598-019-52238-x
Abstract: By combining atomistic and higher-level modelling with solution X-ray diffraction we analyse self-assembly pathways for the IFQINS hexapeptide, a bio-relevant amyloid former derived from human lysozyme. We verify that (at least) two metastable polymorphic structures… read more here.
Keywords: control parallel; shape; versus antiparallel; kinetic control ... See more keywords
Manipulating the inorganic motif by kinetic control of antimony halide organic-inorganic hybrid materials for larger Stokes shift and significantly enhanced quantum efficiency.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04401c
Abstract: Adjusting the structure of the inorganic components has been proved to be an efficient method for the performance optimization of organic-inorganic hybrid materials. One particular organic ligand can typically form numerous hybrid structures with one… read more here.
Keywords: quantum efficiency; inorganic hybrid; organic inorganic; antimony halide ... See more keywords
Fabrication of a family of atomically precise silver nanoclusters via dual-level kinetic control
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01016j
Abstract: The controllable preparation of metal nanoclusters in high yield is an essential prerequisite for their fundamental research and extensive application. Here a synthetic approach termed “dual-level kinetic control” was developed to fabricate a family of… read more here.
Keywords: dual level; level kinetic; silver nanoclusters; kinetic control ... See more keywords
Thermodynamic vs. Kinetic Control in Synthesis of O-Donor 2,5-Substituted Furan and 3,5-Substituted Pyrazole from Heteropropargyl Precursor
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27165178
Abstract: Elaboration of a convenient route towards donor-substituted pyrazoles from heteropropargyl precursors is challenging due to a number of thermodynamically favorable side reactions (e.g., acetylene–allene isomerization and Glaser homocoupling). In this work, Sonogashira cross-coupling conditions of… read more here.
Keywords: thermodynamic kinetic; control; control synthesis; kinetic control ... See more keywords