Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03898
Abstract: Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was… read more here.
Keywords: valence tautomeric; effect valence; discovery kinetic; kinetic effect ... See more keywords
Electric-Double-Layer Origin of the Kinetic pH Effect of Hydrogen Electrocatalysis Revealed by a Universal Hydroxide Adsorption-Dependent Inflection-Point Behavior.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01164
Abstract: The mechanism of the kinetic pH effect in hydrogen electrocatalysis, that is, the order-of-magnitude kinetic gap between the hydrogen oxidation and evolution reactions (HOR/HER) in acidic and alkaline electrolytes, has been drastically explored but still… read more here.
Keywords: hydrogen electrocatalysis; kinetic effect; inflection point; hydrogen ... See more keywords
High-temperature quantum kinetic effect in silicon nanosandwiches
Sign Up to like & getrecommendations! Published in 2017 at "Low Temperature Physics"
DOI: 10.1063/1.4974190
Abstract: The negative-U impurity stripes confining the edge channels of semiconductor quantum wells are shown to allow the effective cooling inside in the process of the spin-dependent transport, with the reduction of the electron-electron interaction. The… read more here.
Keywords: temperature; temperature quantum; high temperature; quantum kinetic ... See more keywords